Calculating limiting oxygen concentration of gas mixtures

Authors

DOI:

https://doi.org/10.46299/j.isjea.20230202.13

Keywords:

Loc, lower exlosion limit, upper exlosion limit

Abstract

The limit values for the fuel concentration in the air-flammable fuel mixture are LEL (lower explosive limit) and UEL (upper explosive limit). The addition of an inert component to the fuel / air mixture determines the increase and decrease of the LEL, until no explosion occurs. The maximum oxygen quantity of the non-combustible - air - inert fuel mixture is LOC (limited oxygen concentration), an important safety property. Investigation of a comprehensive set of data on the flammability at high temperature and ambient pressure obtained from documented sources was carried out for systems containing nitrogen, carbon dioxide and water (steam) such as inert ingredients. Determining the LOC for gas mixtures with different ratios requires step-by-step testing. To solve that problem, the author used Lechateler calculation method to calculate LOC for the ratio of gas mixture and compared the results of experimental equipment.

References

ASTM International, 2008b. ASTM International Standard test methods for limiting oxygen (oxidant) concentration in gases and vapors.

Brandes and Ural, 2008. Ural. Towards a global standard for flammability determination.

Kondo et al., 2006. Extended Le Chatelier's formula and nitrogen dilution effect on the flammability limits.

Kondo et al., 2008. S. Kondo, K. Takizawa, A. Takahashi, K. Tokuhashi, A. Sekiya. A study on flammability limits of fuel mixtures.

Schroder and Molnarne, 2005. Flammability of gas mixtures. Part I: fire potential.

E. Brandes, W. Moller, Sicherheitstechnische Kenngr ¨ oßen, Band 1 ˝ (Brennbare Flussigkeiten und Gase), Wirtschaftsverlag NW, Bremer- ¨ haven, 2003.

M. Molnarne, Th. Schendler, V. Schroder, Sicherheitstechnis- ¨ che Kenngroßen Band 2 (Explosionsbereiche von Gasgemischen), ˝ Wirtschaftsverlag NW, Bremerhaven, 2003.

[3] prEN 14756, Determination of the limiting oxygen concentration (LOC) for gases and vapours, CEN/TC 305 (2003).

EN 1839, Determination of Explosion Limits of Gases and Vapours, Beuth Verlag GmbH, 2003.

O. Fuß, M. Molnarne, V. Schroder, A. Sch ¨ onbucher, Determination of ¨ new group contributions to calculate limiting oxygen concentrations, Chem. Eng. Technol. 26 (2003) 428–433.

O. Fuß, M. Molnarne, A. Schonbucher, V. Schr ¨ oder, Limiting oxygen ¨ concentrations of combustible gases and vapours, Chem. Ing. Technik 75 (2003) 101–104.

O. Fuß, M. Molnarne, A. Schonbucher, V. Schr ¨ oder, Determination of ¨ new increments for the calculation of limiting oxygen concentrations, Chem. Ing. Technik 74 (6) (2002) 827–832.

D. Markus, H. Schildberg, W. Wildner, G. Krzdalic, U. Maas, Flammability limits of premixed methane/methanol/air flames, Comb. Sci. Technol. 175 (2003) 2095–2105.

D. Markus, U. Maas, Calculation of explosion limits with detailed reaction kinetics, Chem. Ing. Technik 76 (2004) 289–292.

G. Melhem, A detailed method for estimating mixture flammability limits using chemical equilibrium, Proc. Safety Progr. 16 (1997) 203.

D. Razus, M. Molnarne, O. Fuß, Limiting oxygen concentration evaluation in flammable gaseous mixtures by means of calculated adiabatic flame temperatures, Chem. Eng. Process. 43 (2004) 775– 784

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Published

2023-04-01

How to Cite

Truong, Q. V., & Ngo, T. H. (2023). Calculating limiting oxygen concentration of gas mixtures. International Science Journal of Engineering & Agriculture, 2(2), 142–146. https://doi.org/10.46299/j.isjea.20230202.13